Beilstein J. Org. Chem.2014,10, 2484–2500, doi:10.3762/bjoc.10.260
; counter electrode reaction; electrocarboxylationmechanism; reactor setup; Introduction
Carbon dioxide recycling
Implementing sustainable, resource-efficient chemical processes to meet the world’s growing demand for energy and chemicals is one of today’s major challenges. Depletion of fossil resources
anodic reactions for the electrocarboxylation of 1,3-butadiene.
General mechanism for electrocarboxylation of alkynes.
Electrocarboxylation of ethyl cinnamate [70].
General electrocarboxylationmechanism for carbonyl compounds (Y = O) and imines (Y = NH) [75][76][77].
Electrocarboxylationmechanism of
PDF
Graphical Abstract
Scheme 1:
Synthesis of salicylic acid and p-hydroxybenzoic acid via Kolbe–Schmidt reaction [16-20].